Tiny spectrometer…huge possibilities

Researchers at North Carolina State University (NCSU; Raleigh, NC) have designed and demonstrated a spectrometer that’s just a few square millimeters in size, which is several orders of magnitude smaller than conventional technologies, and sensitive enough to accurately measure a broader range of wavelengths than is currently possible.

The new technology involves a tiny photodetector that senses light after it interacts with a target material. And when different low voltages are applied, the team says they can manipulate which wavelengths—ranging from ultraviolet to near-infrared—the photodetector is sensitive to (see video).

“In our case, the voltage sweep is relatively small, from about -0.8 to 0.2 V,” says Brendan O’Connor, a professor in NCSU’s Department of Mechanical and Aerospace Engineering. “More specifically, the way we get the unique photoresponse with applied voltage is by having two photosensitive cells stacked on top of each (in a tandem) designed in such a way that the efficiency of charge extraction from each cell depends on the applied voltage.”

Each cell has a unique spectral absorption character, despite some overlapping absorption. This combination from each of the cells allows the spectrum of the incoming light source to be reconstructed after the detector is calibrated or trained.

How it started

The team’s spectrometer design comes after previous work on polarization-sensitive photodetectors.

“We realized we could use polarization for color selectivity in a photodetector design,” O’Connor says. But the team also discovered that achieving hyperspectral detection with their design “resulted in a rather complicated device stack,” prompting them to turn toward the periphery of miniaturized spectrometers.

“We saw a review in Science on miniaturizing spectrometers,” O’Connor says. “The discussion on reconstruction spectrometers inspired us to figure out how we could do this with organic detectors.”

After testing their device, the NCSU team looked at older work relating to amorphous silicon detectors that used a similar design. But it wasn’t used for spectral detection; it was used for two- and three-color detection. O’Connor says they also found a similar design that used organic semiconductors. But again, it was used only for two optical bands.

“Our design is unique in that the materials used in the cell were specifically selected and implemented in our device design that would lead to spectrometer capabilities,” O’Connor explains.

How it’s going

The pixel-sized spectrometer operates very quickly; the entire process happens in less than a millisecond. And it’s already proven to be as accurate as conventional spectrometers, with sensitivity that rivals commercial photodetection devices.

“Moving to a single photodetector element allows for simple miniaturization that is very difficult to achieve using dispersive optics and filters,” O’Connor says, noting the design doesn’t need additional optical elements. “Having a monolithic, two-terminal device allows for simple integration into an array of detectors.”

While akin to a CCD camera in a smartphone, the team’s device doesn’t need RGB color filters. Instead, each pixel would have spectrometer capabilities, paving the way for a compact imaging spectrometer.

There have been demonstrations using an applied voltage to a photodetector to realize a reconstruction spectrometer, including some that use semiconductors, O’Connor points out. But he says his team’s work has produced a much more “simple and effective design that outperforms these recent remonstrations in many respects, including speed, power, bandwidth, resolution, etc.”

As a result, a wide array of applications is possible for the new tiny spectrometer.

“The spectral information from a target material provides a wealth of information,” O’Connor says.

It could be used in laboratory settings—as a microscope attachment, for example—as well as in manufacturing for quality control, and in health monitoring and other biosensing applications. There is also potential for consumer products, such as those used to treat skin conditions, food quality detection, or to identify early stages of plant disease. Other possibilities include monitoring car exhaust, inspecting dyes used in foods and clothing, verifying health supplements, and security and optical encryption.

“The list goes on,” O’Connor says. “It’s exciting to think about what is possible for a powerful piece of equipment that’s usually relegated to research laboratories to be put into people's hands. Scaling this technology down to consumer products would bring this type of scientific value to everyday uses.”

What’s next?

O’Connor cites several improvements the team is now working on. Among them, broadening the device’s operating bandwidth and making the detector even faster, as well as improving the detector calibration and reconstruction algorithm.

“While we can reproduce a broad array of incoming light spectra, the detector could improve in capturing fine spectral features,” O’Connor says. “We believe this is more of a challenge in the reconstruction model rather than the detector itself.”

The team also plans to translate the detector to an imaging array.

“The photodetector we demonstrated is not too different from an OLED fabricated as an array in AMOLED displays. Although our case should actually be simpler in many ways,” O’Connor says. “We would like to develop an array that can take fast images capturing spatial and spectral information, and if fast enough, videos. This would open up that wide range of applications. There are far-reaching opportunities with this technology, and we’re excited to see where it goes next.”