Zinc oxide (ZnO) is an attractive material among direct-bandgap semiconductors. Due to its large bandgap energy and large exciton binding energy, the material has light-emitting properties as well as the ability to sustain a large electric field that enables it to power electronic devices because of its large bandgap energy and large exciton binding energy.
A recent study done by Kazunobu Kojima and Shigefusa Chichibu of Tohoku University (Sendai, Japan) has measured the internal quantum efficiency (IQE) of ZnO crystals for both light-emitting and non-light-emitting processes. In high-quality ZnO crystals, nonradiative recombination centers (NRCs) are an important phenomenon affecting near-band-edge (NBE) emission. NRCs act as undesired energy dissipation channels and reduce the IQE of the NBE emission.
To understand whether the light-emitting process or the non-light-emitting process was more important in determining the behavior of IQE, Kojima and his colleagues measured the IQE values of a ZnO crystal grown by the hydrothermal method. To do so, they employed a technique created by Kojima and fellow researchers known as omnidirectional photoluminescence (ODP) spectroscopy—a nondestructive method for probing semiconducting crystals with light to detect defects and impurities.
The IQE characteristics in ZnO crystals were examined under photopumping conditions. IQE values indicated a constant behavior for weak photopumping conditions and a monotonic increase for strong excitation. Because a significant decrease was observed for the non-light-emitting process with photopumping, the origin of the IQE increase was revealed to be dominated by the deceleration of the non-light-emitting process due to the saturation of NRCs.
"Obtaining a quantitative breakdown of IQE from both processes allows us to better design semiconductors to improve IQE," said Kojima, lead author of the study.
The result could help lead to very efficient short-wavelength LEDs.
Source: http://www.tohoku.ac.jp/en/press/accelerate_decelerate_light_emitting_zno.html
REFERENCE:
1. Kazunobu Kojima and Shigefusa F. Chichibu, Applied Physics Express (2020); https://doi.org/10.35848/1882-0786/abcd73.
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