Three Decades Later, Metallic Oxygen Finally Yields Its Raman Signature

The vibrational properties of metallic oxygen have remained inaccessible until now. Here Raman spectra over a broad pressure range are captured thanks to the combination of diamond anvil cell techniques with highly stable singlefrequency lasers.
Sept. 28, 2026

Although oxygen is known to become metallic at high pressures, its vibrational properties have remained largely inaccessible for more than three decades because of the combined challenges of weak Raman scattering, high reflectivity of metallic samples, and the demanding environment of diamond anvil cell experiments.
Here we show that these challenges can be overcome through exceptional instrument performance. Using highly stable single-frequency laser sources, high-fidelity spectra were collected establishing new benchmarks for exploring matter at extreme conditions.